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Dr. Jordan Tsenov Laboratory of Structural Organic Anaysis Institute of Organic
Chemistry Acad. G. Bonchev Str.,
Build. 9 Tel: +359 2 9606125 Fax: +359 2 8700225 e-mail: jtsenov@orgchm.bas.bg |
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1947 Born in Ohoden, Bulgaria.
1970 Master of Science in Organic Synthesis at the University of Chemical Technology and Metallurgy, Sofia.
1976 Research Associate at IOCCP
1998 PhD at IOCCP, Bulgarian Academy of Sciences. 2007 PhD at IOCCP, Bulgarian Academy of Sciences. Thesis: IR Spectra and structure of nitriles, isocyanides and their anions: comparative experimental and theoretical study, Scientific supervisor: Acad. I. Juhnovski.
1999 Senior Research Associate at IOCCP
Scientific Interests:
Physical organic chemistry;
Vibrational spectroscopy;
Quantum-chemical calculations;
Structural organic analysis;
Chemistry and spectroscopy of carbonyl and cyanocompounds, their ions and adducts, isotope labelled compounds;
Participation in Projects:
1995-1997, Spectrochemistry of conjugated organic molecules and ions, granted by the Bulgarian National Science Fund, Contract Chemistry-442.
1997-1999, Synthesis, spectral investigation and X-Ray study of squaric acid derivatives - new materials for nonlinear optics, granted by the Bulgarian National Science Fund, Contract Chemistry-605.
1999-2001, Experimental and ab initio MO spectrochemistry of organic systems: neutral molecules, hydrogen bonded complexes and ions, granted by the Bulgarian National Science Fund, Contract Chemistry-801.
2003-2005, Organic molecules, radicals, ions and hydrogen-bonded complexes: chemical, physical and theoretical studies, granted by the Bulgarian National Science Fund, Contract Chemistry-1213.
2005-2008, Organic molecules, radicals, ions and hydrogen-bonded complexes: chemical, physical and theoretical studies, granted by the Bulgarian National Science Fund, Contract Chemistry-1510.
Selected Publications:
I.N. Juchnovski, J.A. Tsenov, I.G. Binev. Infrared Spectra and Structure of Alkane- and Cycloalkanecarbonitriles and of Their Carbanions: An ab initio Force Field Treatment. Spectrochim. Acta Part A 52, 1996, 1145-1154.
I. G. Binev, J. A. Tsenov, E. A. Velcheva , V. B. Radomirska, I. N. Juchnovski. Infrared Spectra and Structure of the Isomeric (Cyanophenyl)acetonitriles and of Their Carbanions: An ab initio Force Field Treatment. J. Mol. Struct., 378, 1996, 133-146.
J. A. Tsenov, I. G. Binev, I. N. Juchnovski. IR Spectral and Structural Changes of Phenyl Isocyanides and Benzonitriles, Accompanying Their Conversion into Anion-Radicals: ab initio and Experimental Studies. C. R. Acad. Bulg. Sci., 51,(1-2), 1998, 57-60.
I. G. Binev, B. A. Stamboliyska, Y. I. Binev, E. A. Velcheva, J. A. Tsenov. IR spectra and structure of 1-H-isoindole-1,3(2H)-dione (phthalimide), cis-hexahydro-1-H-isoindole-1,3(2H)-dione (hexahydrophthalimide) and of their nitranions. J. Mol. Struct., 513, 1999, 321-343.
Y. G. Binev, R. R. Petrova, J. A. Tsenov, I. G. Binev. IR spectra and structure of (4-nitrophenyl)acetonitrile and of its carbanion: experimental and ab initio studies. J. Mol. Struct., 516, 2000, 23-29.
Stamboliyska, B.A., Binev, Y.I., Radomirska, V.B., Tsenov, J.A., Juchnovski, I.N., IR spectra and structure of 2,5-pyrrolidinedione (succinimide) and of its nitranion: Experimental and ab initio MO studies, J. Mol. Struct. 516 (2000) 237-245.
Binev, Y.I., Tsenov, J.A., Juchnovski, I.N., Binev, I.G., Ab initio, DFT and experimental studies on the IR spectra and structure of propanedinitrile (malononitrile) and its carbanion, J. Mol. Struct. Theochem. 625 (2003) 207-214.
Dimitrova, Y., Tsenov, J.A., Ab initio and DFT studies of the structure, stability and vibrational spectrum of the hydrogen-bonded (CH3)2O:HONO 2 complex, J. Mol. Struct. Theochem. 683 (2004) 65-70.
Mavrova, A.Ts., Anichina, K.K., Vuchev, D.I., Tsenov, J.A., Kondeva, M.S., Micheva, M.K., Synthesis and antitrichinellosis activity of some 2-substituted-[1,3] thiazolo[3,2-a]benzimidazol-3(2H)-ones, Bioorg. Med. Chem. 13 (2005) 5550-5559.
Mavrova, A.Ts., Anichina, K.K., Vuchev, D.I., Tsenov, J.A., Denkova, P.S., Kondeva, M.S., Micheva, M.K., Antihelminthic activity of some newly synthesized 5(6)-(un)substituted-1H-benzimidazol-2-ylthioacetylpiperazine derivatives, Eur. J. Med. Chem. 41 (2006) 1412-1420.
Dimitrova, Y., Tsenov, J.A., Theoretical study of the structures and vibrational spectra of the hydrogen-bonded systems of 4-cyanophenol with N-bases, Spectrochim. Acta A68 (2007) 454-459.
J. Tsenov, S. Stoyanov, I. Binev, Experimental and computational studies on the IR spectra and structures of the free tricyanomethanide carbanion and its potassium ion-pair, Bulg. Chem. Comm. 37 (2005), 361.
J. Tsenov, S. Stoyanov, I. Binev, IR Spectral and structural changes, caused by the conversion of 4-cyanobenzamide into azanion: a combined experimental/computational approach, Bulg. Chem. Comm. (2008) in press.
S. Stoyanov, A. Popova , J. Tsenov, IR Spectra and structure of 3,5,5-trimethyl(cyclohex-2-enylidene) malononitrile and its potassium cyanide and sodium methoxide carbanionic adducts: experimental and b3lyp studies, Bulg. Chem. Comm. (2008) in press.